A many-particle derivation of non-Markovian kinetic equations of reversible reaction A+B⇌C in solutions based on the effective pairs approach

✍ Scribed by A.A. Kipriyanov; A.B. Doktorov

• Book ID: 104340859
• Publisher: Elsevier Science
• Year: 2003
• Tongue: English
• Weight: 350 KB
• Volume: 326
• Category: Article
• ISSN: 0378-4371
• DOI: 10.1016/s0378-4371(03)00288-7

✦ Synopsis

The non-Markovian kinetic equations for local concentrations have been derived in the e ective pairs approximation on the basis of the hierarchy for correlation patterns of the reversible reaction A + B C. The equations are shown to agree with the kinetic and thermodynamic detailed balancing principles. As compared to the integral encounter theory equations obtained earlier, the above equations have a wider time range of applicability, and may form the basis for the development of a binary approximation for the reversible reaction A + B C in solutions.