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A RuH2(CO)(PPh3)3-Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon−Hydrogen Bond Cleavage

✍ Scribed by Kakiuchi, Fumitoshi; Matsuura, Yusuke; Kan, Shintaro; Chatani, Naoto


Book ID
111952563
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
427 KB
Volume
127
Category
Article
ISSN
0002-7863

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ChemInform Abstract: RuH2(CO)(PPh3)3-Cat
✍ Kentaroh Kitazawa; Masashi Kotani; Takuya Kochi; Michael Langeloth; Fumitoshi Ka 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB

## Abstract Ru‐catalyzed arylation of benzoic acid esters with electron‐rich arylboronates proceeds regioselectively at the ortho‐position to give sterically hindered benzoates, e.g. (III), (V) in good yields.