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Regioselective Alkenylation of Aromatic Ketones with Alkenylboronates Using a RuH2(CO)(PPh3)3 Catalyst via Carbon—Hydrogen Bond Cleavage.

✍ Scribed by Satoshi Ueno; Naoto Chatani; Fumitoshi Kakiuchi


Publisher
John Wiley and Sons
Year
2007
Weight
31 KB
Volume
38
Category
Article
ISSN
0931-7597

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ChemInform Abstract: RuH2(CO)(PPh3)3-Cat
✍ Kentaroh Kitazawa; Masashi Kotani; Takuya Kochi; Michael Langeloth; Fumitoshi Ka 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB

## Abstract Ru‐catalyzed arylation of benzoic acid esters with electron‐rich arylboronates proceeds regioselectively at the ortho‐position to give sterically hindered benzoates, e.g. (III), (V) in good yields.