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ChemInform Abstract: RuH2(CO)(PPh3)3-Catalyzed Arylation of Aromatic Esters Using Arylboronates via C—H Bond Cleavages.

✍ Scribed by Kentaroh Kitazawa; Masashi Kotani; Takuya Kochi; Michael Langeloth; Fumitoshi Kakiuchi

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201033088

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✦ Synopsis

Abstract

Ru‐catalyzed arylation of benzoic acid esters with electron‐rich arylboronates proceeds regioselectively at the ortho‐position to give sterically hindered benzoates, e.g. (III), (V) in good yields.

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