plenary lectures, namely, by Prof.
A report on the Twenty-fifth Symposium on Heteroatom Chemistry of the Chemical Society of Japan
โ Scribed by Satoshi Ogawa; Shigeru Oae
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 333 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
โฆ Synopsis
This article summarizes the four plenary lectures and 53 oral communications and provides the titles of 50 posters presented at the meeting that included 262 participants.
The first plenary lecture was presented by Prof. N. Tokitoh on "New Aspects in the Chemistry of Heteroatom-Containing Multiple Bonds." The first part of the lecture covered his area of interest about the age-old subject of the synthesis of tremendously crowded compounds, low-coordinate organoheteroatom compounds, such as divalent species of heavier group 14 elements 1; doubly bonded species of heavier group 14 elements 2; and a series of group 14 and 16 double-bonded compounds 3. He also showed the synthesis of the first examples of stable sila-aromatics, silabenzene 4 and silanaphthalene 6, and the first isolation of a stable distibene 5a and
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When an โฃ-seleno carbonyl compound was reacted with an aldehyde in the presence of TiCl 4 and Ph 3 P, a highly stereoselective formation of an aldol derivative could be realized. Highly stereoselective reactions of b-trimethylsilylsulfoxides were also described.
The 18th Symposium, organized by Professor Katsuyuki Ogura of Chiba Institute of Technology, was very successful, with about 250 participants in attendance. There were 46 oral presentations of 24 minutes each and 4 plenary lectures. The first plenary lecture was presented by Professor Toru Koizumi