✦ LIBER ✦

A report on the 31st Symposium on Heteroatom Chemistry of the Chemical Society of Japan

✍ Scribed by Akihiko Ishii; Yoshiaki Sugihara; Juzo Nakayama

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 242 KB
Volume: 16
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20134

No coin nor oath required. For personal study only.

✦ Synopsis

The first plenary lecture was given by Noboru Ono (Ehime University) on "Development of Organic Thin Film Transistor Based on Fundamental Organic Chemistry." He presented the synthesis of tetrabenzoporphyrins by a retro Diels-Alder reaction. Tetrabenzoporphyrin (1) was synthesized cleanly by heating the precursor 2 having fused bicyclo[2.2.2]octadiene (BCOD) rings. This strategy was extended to the syntheses of a series of highly conjugated porphyrin analogs, including thia-, dithia-, and

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