A Remarkable, Stable Radical–Molecule Complex: HO2⋅CF3C(O)OH
✍ Scribed by Joseph S. Francisco
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 58 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
Hemilabile ligands / Cyclopentadienyl ligands, functionalised / Iron compounds / Halfsandwich complex Reaction of iron(I1) chloride with one equivalent of [MeO-[MeO(CH2CH20)3(CH2)3C5Me4]Fe(C5H5) (2) and [MeO-(CH2CH20)3(CH2)3C5Me4]Li in THF yields the title halfsand-(CH2CH20)3(CH2)3C5Me4]Fe(CO)2Cl (3
The hydrolysis of [Hg{P(CF 3 ) 2 } 2 (PMe 3 ) 2 ] yields colourless crystals of [Hg{OP(O)CF 3 (OH)} 2 (PMe 3 ) 3 ]. The proposed multistep reaction proceeds via primary hydrolysis of the starting material giving HgO and HP(CF 3 ) 2 . The latter is directly oxidized by HgO to (CF 3 ) 2 P(O)OH. The bi