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A Remarkable, Stable Radical–Molecule Complex: HO2⋅CF3C(O)OH

✍ Scribed by Joseph S. Francisco


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
57 KB
Volume
112
Category
Article
ISSN
0044-8249

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[MeO(CH2CH2O)3(CH2)3C5Me4]FeCl: A Halfsa
✍ Siemeling, Ulrich 📂 Article 📅 1995 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 223 KB 👁 1 views

Hemilabile ligands / Cyclopentadienyl ligands, functionalised / Iron compounds / Halfsandwich complex Reaction of iron(I1) chloride with one equivalent of [MeO-[MeO(CH2CH20)3(CH2)3C5Me4]Fe(C5H5) (2) and [MeO-(CH2CH20)3(CH2)3C5Me4]Li in THF yields the title halfsand-(CH2CH20)3(CH2)3C5Me4]Fe(CO)2Cl (3

Synthesis and Structure of [Hg{OP(O)CF3(
✍ Ingo Pantenburg; Christoph Thösen; Berthold Hoge 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 126 KB 👁 1 views

The hydrolysis of [Hg{P(CF 3 ) 2 } 2 (PMe 3 ) 2 ] yields colourless crystals of [Hg{OP(O)CF 3 (OH)} 2 (PMe 3 ) 3 ]. The proposed multistep reaction proceeds via primary hydrolysis of the starting material giving HgO and HP(CF 3 ) 2 . The latter is directly oxidized by HgO to (CF 3 ) 2 P(O)OH. The bi