A Reevaluation of the Ambident Reactivity of the Guanine Moiety Towards Hydroxyl Radicals
✍ Scribed by Chryssostomos Chatgilialoglu; Mila D'Angelantonio; Maurizio Guerra; Panagiotis Kaloudis; Quinto G. Mulazzani
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 395 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
The electrophilic additions of hydroperoxyl HO , alkylperoxyl RO , 2 2 and halogenated alkylperoxyl radicals to ethylene were studied using the AM1 and PM3 semiempirical MO methods at the SCFrUHF level. Reactantlike transition states were Ž U . predicted for the title additions. The AM1 activation e
## Abstract Alternating guanine–adenine strands of DNA are known to self‐associate into a parallel‐stranded homoduplex at neutral pH, fold into an ordered single‐stranded structure at acid pH, and adopt yet another ordered single‐stranded conformer in aqueous ethanol. The unusual conformers melt co