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Influence of DNA Structure on the Reactivity of the Guanine Radical Cation

✍ Scribed by Francesco Luigi Gervasio; Alessandro Laio; Marcella Iannuzzi; Michele Parrinello

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
257 KB
Volume
10
Category
Article
ISSN
0947-6539

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## Abstract The structure and reactivity of the cysteine methyl ester radical cation, CysOMe^.+^, have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe^.+^ undergoes rapid ion–molecule reactions with dimethyl disulfide, allyl