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A Rapid, Asymmetric Synthesis of the Decahydrofluorene Core of the Hirsutellones

โœ Scribed by Tilley, S. David; Reber, Keith P.; Sorensen, Erik J.

Book ID
124068396
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
162 KB
Volume
11
Category
Article
ISSN
1523-7060

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๐Ÿ“œ SIMILAR VOLUMES

Stereoselective synthesis of the decahyd
Stereoselective synthesis of the decahydrofluorene core of the hirsutellones
โœ Geoff T. Halvorsen; William R. Roush ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 683 KB

A stereoselective synthesis of the decahydrofluorene core of the hirsutellones was accomplished in eight steps and in 43% overall yield. The key step of the synthesis is the highly stereoselective intramolecular Diels-Alder cyclization of the siloxacyclopentene-constrained tetraene 1.

Studies toward the total synthesis of th
Studies toward the total synthesis of the hirsutellones
โœ Mingzheng Huang; Chong Huang; Bo Liu ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 390 KB

A strategy of tandem ketene-trapping/IMDA toward the total synthesis of the hirsutellones was attempted. The AB ring moiety of the hirsutellones was constructed with the proper stereochemistry.