A radical-cation initiated polymerization of n-vinylcarbazole
β Scribed by Harvey Scott; Glen A. Miller; Mortimer M. Labes
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- French
- Weight
- 294 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Ithe~~~c~~tnit~lkmeaca~ea utlonic polymariaatioll of N-vinylcubasola at or aMe ita r.p., ti it is poatnlatad ulatinitlat1on involvxta protontranafer from catalyatto . monomer'. We have found that a solution polymerinatlon vltb rmendnt ~bilar
π SIMILAR VOLUMES
In this communication, we first used [60]fullerene as initiator to initiate the bulk polymerization of N-vinylcarbazole (NVC) monomer at 70Β°C (slightly higher than the melting point temperature, 65Β°C, of NVC). A reasonable polymerization reaction pathway via C 60 -NVC ion-radical pairs is suggested.
## Abstract **Summary:** Wellβdefined poly(__N__βvinylcarbazole) [poly(NVC)] was synthesized by macromolecular design via interchange of the xanthates (MADIX)/reversible additionβfragmentation chain transfer (RAFT) polymerization. The homopolymers with controlled molecular weights ($\overline M \_{