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Polymerization of N-vinylcarbazole initiated by carbon black surface

โœ Scribed by K. Ohkita; N. Tsubokawa; M. Noda; M. Uchiyama


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
169 KB
Volume
15
Category
Article
ISSN
0008-6223

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๐Ÿ“œ SIMILAR VOLUMES


Bulk polymerization of N-vinylcarbazole
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In this communication, we first used [60]fullerene as initiator to initiate the bulk polymerization of N-vinylcarbazole (NVC) monomer at 70ยฐC (slightly higher than the melting point temperature, 65ยฐC, of NVC). A reasonable polymerization reaction pathway via C 60 -NVC ion-radical pairs is suggested.

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In order to obtain more detailed information on the mechanism of the polymerization of N-vinylcarbazole (N-VC) in the presence of carbon black, a comparison of the rates of conversion under various conditions was made and the following results were obtained. The phenolic hydroxyl groups on the surfa

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โœ R.G. Jones; N. Khalid ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 302 KB

Azobisisobutyronitrile, as a photosensitizer of the polymerization of N-vinylcarbazole in dichloromethane solution at 2 = 366nm, has also been shown to quench the polymerization that normally occurs in its absence. As the initiator concentration is raised, the polymer yields at first decrease and pa