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A Protocol for an Asymmetric Synthesis of γ-Amino Acids

✍ Scribed by Rajender Reddy, Leleti; Prasad, Kapa; Prashad, Mahavir

Book ID
120544305
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
489 KB
Volume
77
Category
Article
ISSN
0022-3263

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✍ Deepak M. Shendage; Roland Fröhlich; Klaus Bergander; Günter Haufe 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 1 views

## Abstract Asymmetric alkylation of (__S__)‐Boc‐BMI (**1a**, BMI = 2‐__tert__‐butyl‐3‐methylimidazolidin‐4‐one) and its α‐methyl derivative **1b** with 2‐fluoroallyl tosylate, subsequent mild acidic deprotection of the products **2a** and **2b**, and basic hydrolysis of the thus formed __N__‐methy