A product study of the OH radical-initiated oxidation of isoprene: formation of C5-unsaturated diols
โ Scribed by Lars Ruppert; Karl Heinz Becker
- Book ID
- 114380486
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 219 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1352-2310
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Rate constants for several intermediate steps in the OHโinitiated oxidation of isoprene were determined using laserโphotolysis/laserโinduced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K. The rate constant for decomposition of the hydroxyalkoxy radical was
## ฯช12 ฯช1 ฯช1 9 ฯซ 10 mol s of 2) for the reaction of isoprene-based hydroxyalkyl peroxy radicals with NO.
Using a relative kinetic technique, rate coefficients have been measured, at 296 ฯฎ 2 K and 740 Torr total pressure of synthetic air, for the gas-phase reaction of OH radicals with the dibasic esters dimethyl succinate The rate coefficients obtained were (in units of cm 3 molecule ฯช1 s ฯช1 ): dimethy