𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A product predicted with the Felkin–Anh model

✍ Scribed by Hein, S. J. ;Keszler, D. A.

Book ID
114504318
Publisher
International Union of Crystallography
Year
1987
Tongue
English
Weight
322 KB
Volume
43
Category
Article
ISSN
0108-2701

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The Cram Rule Revisited Once More — Revi
The Cram Rule Revisited Once More — Revision of the Felkin−Anh Model
✍ Richard J. Smith; Michael Trzoss; Michael Bühl; Stefan Bienz 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 146 KB 👁 1 views

The reaction mechanism of the LiH addition to α-chiral ketones and acylsilanes was calculated at the ab initio MP2/6-311+G\*\*//RHF/6-31G\* level. The selectivities predicted on the basis of the computed transition states and reaction barriers compare well with the experimental data. For compounds p

Exceptionally high Felkin-Anh control fo
Exceptionally high Felkin-Anh control for the addition of nucleophiles to a β-aminocyclopropylcarbaldehyde
✍ Christian Bubert; Oliver Reiser 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 234 KB

Exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the [3-aminocyclopropylcarbaldehyde 5 in nitroaldol, cyanohydrin, Mukaiyama aldol, and Sakurai reactions, contrasting the low diastereoselectivities generally observed in addit