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ChemInform Abstract: Exceptionally High Felkin-Anh Control for the Addition of Nucleophiles to a β-Aminocyclopropylcarbaldehyde.

✍ Scribed by C. BUBERT; O. REISER

Book ID: 101851164
Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199742092

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Exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the [3-aminocyclopropylcarbaldehyde 5 in nitroaldol, cyanohydrin, Mukaiyama aldol, and Sakurai reactions, contrasting the low diastereoselectivities generally observed in addit

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