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A Potential Intermediate for the Aza-Corey−Chaykovsky Reaction: Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Thiazetidine 1-Oxide

✍ Scribed by Kano, Naokazu; Daicho, Yuya; Kawashima, Takayuki


Book ID
126592700
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
66 KB
Volume
8
Category
Article
ISSN
1523-7060

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Synthesis, structure, and thermolysis of
✍ Naokazu Kano; Xing Jia Hua; Seiji Kawa; Takayuki Kawashima 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 144 KB

1,3,2l 5 -Oxazaphosphetidines bearing the Martin ligand were synthesized by the reaction of the corresponding iminophosphorane and carbonyl compounds and characterized by X-ray crystallographic analysis. Thermolysis of the oxazaphosphetidine gave the cyclic phosphinate and the corresponding imine, i