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Synthesis, Structure, and Thermolysis of a Tetracoordinate 1,2-Oxaboretanide: An Intermediate of the Boron-Wittig Reaction under Basic Conditions

✍ Scribed by Kawashima, Takayuki; Yamashita, Naoko; Okazaki, Renji


Book ID
126135326
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
300 KB
Volume
117
Category
Article
ISSN
0002-7863

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Synthesis, structure, and thermolysis of
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1,3,2l 5 -Oxazaphosphetidines bearing the Martin ligand were synthesized by the reaction of the corresponding iminophosphorane and carbonyl compounds and characterized by X-ray crystallographic analysis. Thermolysis of the oxazaphosphetidine gave the cyclic phosphinate and the corresponding imine, i