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Crystal structure and reactivity of a pentacoordinate 1,2-oxastannetanide: an intermediate of the tin-Peterson reaction

✍ Scribed by Kawashima, Takayuki; Iwama, Naoshi; Okazaki, Renji


Book ID
126271753
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
284 KB
Volume
115
Category
Article
ISSN
0002-7863

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1,3,2l 5 -Oxazaphosphetidines bearing the Martin ligand were synthesized by the reaction of the corresponding iminophosphorane and carbonyl compounds and characterized by X-ray crystallographic analysis. Thermolysis of the oxazaphosphetidine gave the cyclic phosphinate and the corresponding imine, i