Reche values have been dclermined for the binding energies of the outer elecuonic bands of Ihe alN.i fluorides using 40.81 eV uluaviolct photoelectron spectroscopy. An approximate difference of 1.1(l) eV belween experimental and Born model binding enclgin is attributed to polarization effects which
A photoelectron study of the alkali chlorides
β Scribed by R.T. Poole; J.G. Jenkin; R.C.G. Leckey; J. Liesegang
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 345 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Precise values I;ave been determined for the binding energies of -Ihe outer electronic bands of the alkali br&ides and iodides using 40.81 cV.ultiavi?let photoelectron spectroscopy. These values have been corrected for relaxation effects and then favounbly. compared with the Born model for ionic sol
Core and valence electronic levels in the alkali azides were imestigated by X-ray photoelectron spectroscopy with particu!ar emphasis on the levels associated with 'he azide anion. Comparisons are mde to existing molecular orbital calculations, and assignments suggested.
A reference electrode based on the silver e silverchloride reaction has been developed for use in fused halide systems. The electrode (i) Is reproducible to within better than f 10 mV. (ii) Remains constant in e.m.f. over long periods in fused alkali chlorides at 700Β°C and is unaffected by freezing