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A One-Dimensional Thallium(I) Coordination Polymer Involving Polyhapto-Aromatic Interactions

✍ Scribed by Azadeh Askarinejad; Ali Morsali

Publisher
John Wiley and Sons
Year
2006
Tongue
German
Weight
91 KB
Volume
89
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

A one‐dimensional coordination polymer involving Tl ⋅⋅⋅ C interactions, [Tl(μ~4~‐dpa)]~n~(Hdpa = diphenylacetic acid), was synthesized and characterized. The single‐crystal X‐ray data of the compound show that the coordination number of the Tl^I^ ions is five and that Tl centers have an irregular coordination sphere containing a ‘configurationally active’ lone pair/hexahapto (η^6^) interaction, thus resulting in a total hapticity of eleven for a TlC~6~O~5~ environment.

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