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A Novel One-Dimensional Coordination Polymer Involving Weak HgHg Interactions

✍ Scribed by Ali Morsali; Rhett Kempe

Publisher
John Wiley and Sons
Year
2005
Tongue
German
Weight
107 KB
Volume
88
Category
Article
ISSN
0018-019X

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✦ Synopsis

The novel, stable, one-dimensional coordination polymer [Hg 3 (dmap) 6 (m-OAc) 2 ] n {(ClO 4 ) 4 } n (1; dmap 4-(dimethylamino)pyridine) has been synthesized and characterized. Single-crystal X-ray analysis showed that the coordination sphere of the two pertinent, zig-zag-oriented Hg II -atoms is different. One type of Hg-atom in the N 2 O 4 HgÀHgN 2 O 4 environment is seven-coordinate, with a weak HgÀHg interaction. The other type of Hg IIatom in the trans-HgN 2 O 4 units is six-coordinate.

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