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A one-dimensional CdII coordination polymer: poly[[[bis­[methano­lcadmium(II)]-μ2-aqua]-bis­(μ3-pyridine-2,6-dicarboxyl­ato-κ5O:O,N,O′:O′)]

✍ Scribed by Wu, Hui-Fang ;Chen, Xu-Dong ;Du, Miao

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
223 KB
Volume
63
Category
Article
ISSN
1600-5368

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The dinuclear title compound, [Sn~2~(CH~3~)~2~(C~6~H~5~)~2~(C~7~H~3~NO~4~)~2~(H~2~O)~2~]·2CHCl~3~, crystallizes as a dichloroform solvate; the centrosymmetric compound has Sn in a seven-coordinate, __trans__-pentagonal–bipyramidal geometry. The dicarboxylate unit is tetradentate; it binds through th

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.044 wR factor = 0.098 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.