Poly[[tetraaqua-μ2-oxalato-bis(μ3-pyridine-3,4-dicarboxylato-κ4O,O′:O′′:O′′′)diyttrium(III)] trihydrate]
✍ Scribed by Dong, Bao-Xia ;Peng, Jun
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 307 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title yttrium(III) coordination polymer, {[Y~2~(C~7~H~3~NO~4~)~2~(C~2~O~4~)(H~2~O)~4~]·3H~2~O}~n~, has a pyridine-3,4-dicarboxylate (PDC) and oxalate (ox) bridged layer-type structure. The central yttrium ion exhibits a distorted dodecahedral configuration, coordinated by eight O atoms from three PDC ligands, one ox ligand and two uncoordinated water molecules. The ox ligand lies on a center of inversion.
📜 SIMILAR VOLUMES
In the title polymer, [Cu(C 7 H 3 NO 4 )(H 2 O) 2 ] n , the Cu II ion is pentacoordinated and exhibits a distorted square-pyramidal environment formed by one N atom and two O atoms from pyridine-2,4-dicarboxylate ligands and two O atoms from coordinated water molecules. Each pyridine-2,4-dicarboxyla
The dinuclear title compound, [Sn~2~(CH~3~)~2~(C~6~H~5~)~2~(C~7~H~3~NO~4~)~2~(H~2~O)~2~]·2CHCl~3~, crystallizes as a dichloroform solvate; the centrosymmetric compound has Sn in a seven-coordinate, __trans__-pentagonal–bipyramidal geometry. The dicarboxylate unit is tetradentate; it binds through th
bis[aqua-(l-sulfato-j 3 O,O 0 0 0 :O 0 0 00 0 0 )(l-sulfato-j 4 O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 )-(sulfato-jO)terbate(III)] tetrahydrate]