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A Novel Triphosphoramidite Ligand for Highly Regioselective Linear Hydroformylation of Terminal and Internal Olefins

✍ Scribed by Chen, Caiyou; Qiao, Yu; Geng, Huiling; Zhang, Xumu

Book ID: 118735854
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 337 KB
Volume: 15
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol400033k

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## Abstract A highly regioselective hydroaminomethylation of terminal olefins catalyzed by Rh complexes with 2, 2′, 6, 6′‐tetrakis ((diphenylphosphino)methyl)‐1, 1′‐biphenyl (Tetrabi) ligand has been developed. Up to 99 % amine selectivity, 168 linear/branched amine product ratio (__n/i__), and 97.