A Novel Synthesis of Phosphonates from Diethyl (Trichloromethyl)phosphonate
β Scribed by Lowen, Gregory T.; Almond, Merrick R.
- Book ID
- 121825154
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 373 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Phosphonic monoesters are prepared in a two-step procedure by DCC-DMAP mediated esterification of phosphonous acids and oxidation of the resulting phosphonous monoester.
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A stereoselective synthesis of a,@-unsaturated phosphonates based on the reaction of S-(p-oxoa1kyl)dithiophosphates and Se-(p-oxoa1kyl)selenophos- phates with sodium dialkyl phosphites is described.