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A novel synthesis of 2-lithio derivatives of 2-substituted-1,3-dithianes. The addition of organolithium reagents to trimethylenedithio-carbene and to 2-methylene-1,3-dithiane

✍ Scribed by Robert M. Carlson; Paul M. Helquist

Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 149 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)87501-8

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✦ Synopsis

The dithiane synthesis of carbonyl compounds, as developed by Corey and coworkers , involves the conversion of the potential carbonyl carbon into a reactive 2-lithio-1,3-dithiane. We have

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