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A rapid, efficient and selective conversion of aldehydes and acetals to their 1,3-dithiane derivatives with 2,2-dimethyl-2-sila-1,3-dithiane

✍ Scribed by John A Soderquist; Edgar I Miranda

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 156 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87793-x

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✦ Synopsis

Aldehydes and acetals are cleanly and rapidly converted to the corresponding dithianes with 2,2-dimethyl-2-sila-1,3-dithiane and stoichiometric amounts of boron trifluoride etherate even in the presence of ketones, which do not react competitively with the reagent.

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