The first stereoselective total synthesi
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Gowravaram Sabitha; Sambit Nayak; M. Bhikshapathi; J.S. Yadav
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Article
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2009
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Elsevier Science
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French
⚖ 185 KB
The first total synthesis of (3S,4R)-dihydroxy-(6S)-undecyl-a-pyranone 1 and total synthesis of (2S,3R,5S)-(À)-2,3-dihydroxytetradecan-5-olide 2 have been achieved in five steps in a highly stereoselective manner using Maruoka allylation, olefin cross-metathesis, and Sharpless asymmetric dihydroxyla