๐”– Bobbio Scriptorium
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A novel route to alkanes, alcohols, and ethers by dehydrodimerization

โœ Scribed by Stephen H. Brown; Robert H. Crabtree

Book ID
104228084
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
222 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Alkanes, alcohols, and ethers can be conveniently synthesized by homo and cross dimerization using mercury photosensitization. The development of synthetic methods involving the selective activation of C-H bonds is of great current interest. 1 In a previous publication2 we outlined a convenient mercury-photosensitized3 reaction that selectively produces multigram quantities of alkanes, alcohols, and ethers. Many of the compounds are difficult to synthesize by alternate methods but are produced by this system from inexpensive and readily available starting materials (see Eq. l-5).

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