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A novel route to 2-carbamoylcycloalkanones by the addition reaction of silyl enol ethers to isocyanates

✍ Scribed by Iwao Ojima; Shinichi Inaba; Yoichiro Nagai

Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 110 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)87167-7

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✦ Synopsis

Silyl enol ethers are currently much interested in respect to the reaction of enolate anion, and many reports have been made on the formation and spectra of these compounds.

1 Little has been known, however, about the reactivity on the @-carbon of these compounds except trimethylsilylacetals. 2 We have found

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