The reaction of chromyl chloride and O-silylated enolates: a novel regiospecific route to α-hydroxy ketones.
✍ Scribed by Thomas V Lee; Judy Toczek
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 166 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Swrunary: ChromyZ chloride reacts regiospecifically with 0-silylated enolates to form cc-hydroxy ketones.
📜 SIMILAR VOLUMES
A highly regio-and stereoselective Diels-Alder reaction between dienophiles of type I and dienes of type I1 (Scheme I ) gives rise to Diels-Alder adducts of type 111. Upon treatment with BF,. Et,O, these adducts are smoothly converted into the corresponding enones (Scheme 6). Under mild acidic condi
Thermal reaction of butyl N-(p-toluenesulphonyl)iminoacetate and diethyl mesoxalate with ketones leads to the derivatives of f-0x0-d-amino-acids and c-oxo-o(-hydroxy--acids, respectively. 1 b.p's or m.p's and ZR spectra are collected in Table 1 and H NMR data in Table 2. All new compounds gave corre
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