𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A novel rearrangement of an aminoőxy compound

✍ Scribed by Leo A. Paquette

Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
178 KB
Volume
3
Category
Article
ISSN
0040-4039

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✦ Synopsis

A SIZEABLE body of evidence has now accumulated suggesting that a number Of rearrangement reactions proceed via three-membered nitrogen-containing rings.

For example, the Neber rearrangement of ketoxime tosylates, 1 the rearrangement of N,N-dichloro-set-alkylamines, 2-4 and the synthesis of a-amino ketones and acids from N-chloroketimines' have in common the azirine intermediate A (or some closely related aziridine derivative).

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