๐”– Bobbio Scriptorium
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A novel rearrangement: the ring opening of a cyclic azo compound to a diazoalkane

โœ Scribed by C.G. Overberger; Jean-Pierre Anselme


Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
158 KB
Volume
4
Category
Article
ISSN
0040-4039

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Ring-expansion of an aziridinone to a he
โœ Mashitah M Yusoff; Erach R Talaty ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

Reaction of 1,3-di-t,'rt-bu~.laziridinonc (la) and similar aziridinones with thiosemicarbazide affords, as one of the products, a compound devoid of sulfur, vie., a substituted Naminoimidazolidinone (3a) by selective cleavage of the acyl-nitrogcn bond. Compound 3a undergoes a novel, acid-catalyzed r