A novel acid promoted ring-opening polymerization of a seven-membered cyclic carbonate initiated with BCl3

Anionic ring-opening polymerization beha

Anionic ring-opening polymerization behavior of a seven-membered cyclic carbonate; 1, 3-dioxepan-2-one

✍ Jyuhou Matsuo; Fumio Sanda; Takeshi Endo 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 2 views

Anionic ring-opening polymerization of a seven-membered cyclic carbonate, 1,3-dioxepan-2-one ( 1), was carried out to observe that the higher the polymerization temperature and lower the initial monomer concentration were, the lower the yield and molecular weight, and wider the molecular weight dist