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Synthesis of a novel cage compound via oxidative rearrangement of a dihydronaphthofuran

✍ Scribed by Margaret A. Brimble; Richard J.R. Elliott; Peter Turner

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 305 KB
Volume: 54
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)00855-2

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✦ Synopsis

Oxidative rearrangement of dihydronaphthofuran 5 with aqueous ceric ammonium nitrate afforded the cage compound 7 which decomposed to diol 8 upon standing at room temperature. An X-ray structure obtained for diol 8 confirmed the formation of this novel cage structure.

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