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A novel preparative method for α,β-unsaturated oxazolines via α-phenylthiooxazolines

✍ Scribed by J.C. Clinet; G. Balavoine


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
188 KB
Volume
28
Category
Article
ISSN
0040-4039

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The reaction of trialkylstannylmethyllit
✍ Tadashi Sato; Toshihiro Kikuchi; Norio Sootome; Eigoro Murayama 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 224 KB

a,@-Epoxy ketones 2\_, upon treatment with two equivalents of trialkylstannylmethyllithium 1, afforded cyclopropanols 2 as a single product in acyclic system, and a mixture of cyclopropanols 2 and methylene 1,2-diols 2 in cyclic system. Under acidic conditions, the cyclopropanols gave p,y-unsaturate