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Z-Selective or Stereospecific Alkenylation Reaction: A Novel Synthetic Method for α-Fluoro-α,β-unsaturated Esters.

✍ Scribed by Mitsuhiro Yoshimatsu; Yoshinori Murase; Akinori Itoh; Genzoh Tanabe; Osamu Muraoka


Publisher
John Wiley and Sons
Year
2005
Weight
29 KB
Volume
36
Category
Article
ISSN
0931-7597

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A Novel Reaction of β,β'-Dihydroxy Acids or Esters with Vanadium(V) Trichloride Oxide. New Entry to the Stereoselective Synthesis of α-Fluoro-α,β-unsaturated Acids and Esters. -Deoxygenation of various aromatic dihydroxy acids and esters is optimally achieved upon treatment according to conditions