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ChemInform Abstract: A Novel Reaction of β,β′-Dihydroxy Acids or Esters with Vanadium(V) Trichloride Oxide. New Entry to the Stereoselective Synthesis of α-Fluoro-α,β-unsaturated Acids and Esters.

✍ Scribed by T. ISHIHARA; A. SHINTANI; H. YAMANAKA

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Novel Reaction of β,β'-Dihydroxy Acids or Esters with Vanadium(V) Trichloride Oxide.

New Entry to the Stereoselective Synthesis of α-Fluoro-α,β-unsaturated Acids and Esters.

-Deoxygenation of various aromatic dihydroxy acids and esters is optimally achieved upon treatment according to conditions C). The title compounds are obtained stereoselectively with concomitant loss of R-CHO. -(ISHIHARA, T.; SHIN-

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