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A novel planar chiral N-heterocyclic carbene–oxazoline ligand for the asymmetric hydrosilylation of ketones

✍ Scribed by Yongqing Kuang; Xiaoli Sun; Hui Chen; Peng Liu; Ru Jiang


Book ID
118427038
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
376 KB
Volume
10
Category
Article
ISSN
1566-7367

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A novel class of chiral glycosyl-triazole-based P,N ligands were synthesized by click chemistry and were applied to the Rh-catalyzed asymmetric hydrosilylation of a range of substituted acetophenones. Enantioselective hydrosilylation of acetophenone gave (S)-1-phenylethanol in moderate enantioselect