A Novel 1-Glycosyl-1H-triazole-Based P,N
โ
Chao Shen; Peng-Fei Zhang; Xin-Zhi Chen
๐
Article
๐
2010
๐
John Wiley and Sons
๐
German
โ 170 KB
A novel class of chiral glycosyl-triazole-based P,N ligands were synthesized by click chemistry and were applied to the Rh-catalyzed asymmetric hydrosilylation of a range of substituted acetophenones. Enantioselective hydrosilylation of acetophenone gave (S)-1-phenylethanol in moderate enantioselect