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ChemInform Abstract: A Novel 1-Glycosyl-1H-triazole-Based P,N Ligand for Rhodium-Catalyzed Asymmetric Hydrosilylation of Ketones.

โœ Scribed by Chao Shen; Peng-Fei Zhang; Xin-Zhi Chen


Publisher
John Wiley and Sons
Year
2011
Weight
31 KB
Volume
42
Category
Article
ISSN
0931-7597

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A Novel 1-Glycosyl-1H-triazole-Based P,N
โœ Chao Shen; Peng-Fei Zhang; Xin-Zhi Chen ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 170 KB

A novel class of chiral glycosyl-triazole-based P,N ligands were synthesized by click chemistry and were applied to the Rh-catalyzed asymmetric hydrosilylation of a range of substituted acetophenones. Enantioselective hydrosilylation of acetophenone gave (S)-1-phenylethanol in moderate enantioselect