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Chiral N-Heterocyclic Carbene/Pyridine Ligands for the Iridium-Catalyzed Asymmetric Hydrogenation of Olefins

✍ Scribed by Schumacher, Andreas; Bernasconi, Maurizio; Pfaltz, Andreas

Book ID
120541397
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
499 KB
Volume
52
Category
Article
ISSN
0044-8249

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Chiral Phosphino- and (Phosphinooxy)-Sub
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Chiral Phosphino- and (Phosphinooxy)-Sub
Chiral Phosphino- and (Phosphinooxy)-Substituted N-Heterocyclic Carbene Ligands and Their Application in Iridium-Catalyzed Asymmetric Hydrogenation
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## Abstract Enantiomerically pure iridium complexes with phosphino‐ and (phosphinooxy)‐substituted N‐heterocyclic carbene (NHC) ligands were synthesized. Investigation of their electronic properties showed a similar __trans__ influence of the phosphino (or phosphinooxy) and the NHC units. The compl