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A Novel Palladium-Catalyzed Asymmetric Cyclocarbonylation of Allylic Alcohols to γ-Butyrolactones

✍ Scribed by Dr. Wing-Yiu Yu; Dr. Corinne Bensimon; Prof. Howard Alper


Book ID
102792889
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
882 KB
Volume
3
Category
Article
ISSN
0947-6539

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ChemInform Abstract: The First Stereosel
✍ M. BRUNNER; H. ALPER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

The First Stereoselective Palladium-Catalyzed Cyclocarbonylation of β,γ-Substituted Allylic Alcohols. -A catalytic method allowing the synthesis of α,β-substituted-γ-butyrolactones from the title alcohols in modest to good yields is presented. In most cases, this transformation occurs with complete