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Titanocene-Catalyzed Cyclocarbonylation of o -Allyl Aryl Ketones to γ-Butyrolactones

✍ Scribed by Kablaoui, Natasha M.; Hicks, Frederick A.; Buchwald, Stephen L.

Book ID
127261615
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
352 KB
Volume
119
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Titanocene-Catalyze
ChemInform Abstract: Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to . gamma.-Butyrolactones.
✍ N. M. KABLAOUI; F. A. HICKS; S. L. BUCHWALD 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to . gamma.-Butyrolactones. -The first catalytic method for the formation of γ-butyrolactones from enones containing an arylketone moiety using Cp2Ti(PMe3)2 or Cp2Ti(CO)2 is developed. The mechanism of this catalytic hetero Pauson-Khan