## Latifolin (Id) Is an important memter of the neoflavanoia group of -pwa6. AS recently descriteal its synthesis Involves an ionic coupling of trlmethoxy benzene tc,) and o-methoxy clnnamyl ceticn CC9>, the latter being generated from o-methoxp clnnamyl chloride by a Lewis acid.
A novel oxidative skeleton rearrangement of the caffeine system
β Scribed by Zimmer, Hans; Amer, Adel; Ho, Douglas; Koch, Klaus; Schumacher, Christian; Wingfield, Robert C.
- Book ID
- 118050971
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 237 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The addition of an acetyl radical on caryophyllene leads to formation of the four isomeric ketones 5-8 involving a novel rearrangement of the caryophyllene skeleton. The acid catalyzed rearrangement of caryophyllene 1 has been studied in detail'. The final re-\_ action products are clovene 2, caryo
## Abstract On treatment with phosphorus oxychloride, the decalin derivative 6 underwent rearrangement yielding principally the perhydroazulene derivative 8. Similar rearrangement was also observed on dehydration of the decalin derivative 9.
A facile CAN-mediated oxidative rearrangement of monoterpenes of the pinene family to afford bisamides and ether derivatives is described.