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Novel rearrangement during dehydration. Construction of the guaianolide skeleton

✍ Scribed by Ajoy K. Banerjee; William Vera

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
214 KB
Volume
112
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

On treatment with phosphorus oxychloride, the decalin derivative 6 underwent rearrangement yielding principally the perhydroazulene derivative 8. Similar rearrangement was also observed on dehydration of the decalin derivative 9.

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