✦ LIBER ✦

Novel Base-Catalyzed Rearrangement of the Taxane Skeleton 1

✍ Scribed by Appendino, Giovanni; Fenoglio, Ivana; Vander Velde, David G.

Book ID: 127301011
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 102 KB
Volume: 60
Category: Article
ISSN: 0163-3864
DOI: 10.1021/np960667s

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A novel rearrangement of the latifolin s

A novel rearrangement of the latifolin skeleton

✍ Darshan Kumari; S.K. Mukerjee; T.R. Seshadri 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 191 KB

## Latifolin (Id) Is an important memter of the neoflavanoia group of -pwa6. AS recently descriteal its synthesis Involves an ionic coupling of trlmethoxy benzene tc,) and o-methoxy clnnamyl ceticn CC9>, the latter being generated from o-methoxp clnnamyl chloride by a Lewis acid.

The Base-catalyzed Rearrangement of 2-Ni

The Base-catalyzed Rearrangement of 2-Nitrobenzenesulfenanilide

✍ Cava, M. P.; Blake, C. E. 📂 Article 📅 1956 🏛 American Chemical Society 🌐 English ⚖ 492 KB

Intramolecular nickel catalyzed cycloadd

Intramolecular nickel catalyzed cycloadditions of bis-dienes: 3 approaches to the taxane skeleton

✍ Paul A. Wender; Marc L. Snapper 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 255 KB

The successful application of the nickel catalyzed, intramolecular [4+4] cycloaddition of bisdienes to the preparation of both the AB and BC ring systems of the taxane diterpenes is described. This cycloaddition methodology provides the basis for a general and efficient route to angularly alkyl-subs

Base-Catalyzed Degenerate Rearrangement

Base-Catalyzed Degenerate Rearrangement of A 1,2,4-Thiadiazole

✍ Gerrit L'abbé; Linda Beenaerts; Françoise Godts; Suzanne Toppet 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 70 KB 👁 1 views

A novel radical induced rearrangement of

A novel radical induced rearrangement of the caryophyllene skeleton

✍ L.M. van der Linde; A.J.A. van der Weerdt 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 188 KB

The addition of an acetyl radical on caryophyllene leads to formation of the four isomeric ketones 5-8 involving a novel rearrangement of the caryophyllene skeleton. The acid catalyzed rearrangement of caryophyllene 1 has been studied in detail'. The final re-\_ action products are clovene 2, caryo

Novel rearrangement during dehydration.

Novel rearrangement during dehydration. Construction of the guaianolide skeleton

✍ Ajoy K. Banerjee; William Vera 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 214 KB

## Abstract On treatment with phosphorus oxychloride, the decalin derivative 6 underwent rearrangement yielding principally the perhydroazulene derivative 8. Similar rearrangement was also observed on dehydration of the decalin derivative 9.