𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Novel Outcome of the Hydroperoxide Rearrangement ‡

✍ Scribed by Hamann, Hans-Jürgen; Liebscher, Jürgen


Book ID
121438947
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
75 KB
Volume
65
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


A rearranged hydroperoxide from the redu
✍ Lai-King Sy; Shi-Man Hui; Kung-Kai Cheung; Geoffrey D. Brown 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 399 KB

Lithium aluminium hydride reduction of artemisinin produces two unexpected rearrangement products in addition to those reported previously. The structure of the major rearrangement product, a tertiary hydroperoxide, was determined by 2D-NMR and chemical reactions. A mechanism is proposed for this re