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A Novel Ligand for the Enantioselective Ruthenium-Catalyzed Olefin Metathesis

โœ Scribed by Axel Kannenberg; Daniel Rost; Stefan Eibauer; Sascha Tiede; Prof. Siegfried Blechert

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
337 KB
Volume
50
Category
Article
ISSN
0044-8249

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## Abstract New N,Nโ€bidentate Schiff base ligands containing the 2โ€quinolyl moiety proved to be effective in conferring high reactivity and moderate to high enantioselectivity (up to 84% __ee__) to the copper(I)โ€catalyzed asymmetric allylic oxidation of various cylic olefins with __tert__โ€butyl per